论文摘要
Alkaline-earth dihalide nanocrystals（NCs） such as SrFCl, owing to their high chemical stability and low phonon energy, are excellent host materials for lanthanide(Ln3+) doping to achieve desirable optical properties for various bioapplications, Herein, we report a novel strategy for the synthesis of sub-10 nm Ln3+-doped SrFCl NCs with efficient upconverting and downshifting luminescence through a facile onestep hot-injection method. Utilizing the temperature-dependent upconverting luminescence（UCL） from the thermally coupled 2H11/2and4S3/2 levels of Er3+, we showed the potential of SrFCl:Yb,Er NCs as sensitive UCL nanoprobes for non-contact thermal sensing with a maximum detection sensitivity of 0.0066 K-1, which is among the highest values for thermal sensing based on Er3+-activated UCL nanoprobes. Furthermore, by employing the intense downshifting luminescence from Tb3+ and Eu3+, we demonstrated the successful use of biotinylated SrFCl:Ce,Tb and SrFCl:Eu3+ nanoprobes for biotin receptor-targeted cancer cell imaging, thus revealing the great promise of SrFCl:Ln3+ nanoprobes for versatile bioapplications.
论文目录
文章来源
类型: 期刊论文
作者: Jiaojiao Wei,Wei Lian,Wei Zheng,Xiaoying Shang,Meiran Zhang,Tao Dai,Xueyuan Chen
来源: Journal of Rare Earths 2019年07期
年度: 2019
分类: 工程科技Ⅰ辑
专业: 化学,材料科学
单位: College of Chemistry, Fuzhou University,CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences
基金: Project supported by the CAS,SAFEA International Partnership Program for Creative Research Teams,the National Natural Science Foundation of China(21771185,11774345,21875250,21650110462),the CAS Youth Innovation Promotion Association(2016277),the Chunmiao Project of Haixi Institutes of the CAS(CMZX-2016-002),Natural Science Foundation of Fujian Province(201710018)
分类号: O657.3;TB383.1
页码: 691-698
总页数: 8
文件大小: 1526K
下载量: 7
相关论文文献
- [1].Extraction of lanthanide ions with N,N,N′,N′-tetrabutyl-3-oxadiglycolamide from nitric acid media[J]. Nuclear Science and Techniques 2017(06)
- [2].GMP-quadruplex-based hydrogels stabilized by lanthanide ions[J]. Science China(Chemistry) 2018(05)
- [3].Study of lanthanide doped zinc oxide nanoparticles synthesized via a sonochemical method[J]. Science China(Physics,Mechanics & Astronomy) 2013(07)
- [4].Syntheses,structure and photoluminescent properties of lanthanide oxalatosulfocarboxylate coordination polymers[J]. Chinese Science Bulletin 2012(14)
- [5].Recent progress in NIR-Ⅱ emitting lanthanide-based nanoparticles and their biological applications[J]. Journal of Rare Earths 2020(05)
- [6].Magnetic molecular materials with paramagnetic lanthanide ions[J]. Science in China(Series B:Chemistry) 2009(11)
- [7].Syntheses,Crystal Structures and Magnetic Properties of Two Nitrophenyl Substituted Nitronyl Nitroxide Radical-lanthanide Complexes[J]. 结构化学 2016(11)
- [8].Ultrathin lanthanide oxides nanomaterials: synthesis, properties and applications[J]. Science Bulletin 2016(18)
- [9].Sonochemical synthesis and characterization of uniform lanthanide orthophosphate(LnPO_4, Ln=La and Ce) nanorods[J]. Rare Metals 2015(05)
- [10].Grouping separation of mixed rare earths from their coexisting aqueous solutions by liquid-column elution[J]. Chinese Journal of Chemical Engineering 2019(08)
- [11].Synthesis,structure and property of serial p-carboxylphenoxyacetate-lanthanide coordination polymers[J]. Chinese Science Bulletin 2009(23)
- [12].Elastic properties and electronic structures of lanthanide hexaborides[J]. Chinese Physics B 2015(09)
- [13].Multifunction bimetallic lanthanide metal organic frame: Color modulation and high efficiency fluorescence sensitization[J]. China Rare Earth Information 2018(04)
- [14].Visible luminescence of lanthanide ions in Ca_3Sc_2Si_3O_(12) and Ca_3Y2Si_3O_(12)[J]. Journal of Rare Earths 2009(04)
- [15].Sorption of lanthanide ions on biochar composites[J]. Journal of Rare Earths 2018(11)
- [16].Novel Lanthanide Cluster Polymers Based on Cubane-like [Ln_4(OH)_4]~(8+) Clusters and Sulfate Anions[J]. 结构化学 2016(03)
- [17].Crystal structures, thermal behavior and biological activities of lanthanide compounds with 2,4-dichlorobenzoic acid and 1,10-phenanthroline[J]. Science China(Chemistry) 2014(11)
- [18].Synthesis, Crystal Structure and Luminescence of One-dimensional Homochiral Terbium (Ⅲ) Coordination Polymers[J]. Chinese Journal of Structural Chemistry 2020(06)
- [19].A microporous lanthanide metal-organic framework containing channels:Synthesis,structure,gas adsorption and magnetic properties[J]. Science China(Chemistry) 2011(09)
- [20].Simulation of the f-d transitions of lanthanide ions in YPO_4 using quantum-chemical calculations[J]. Chinese Physics B 2012(01)
- [21].Controllable stereoselective synthesis of pyrano[3,2-c]quinolines by lanthanide halides catalyzed aza-Diels-Alder reactions[J]. Chinese Science Bulletin 2010(36)
- [22].Polymerization of ε-caprolactone by lanthanide trisborohydrides and crystal structure of [Ce(BH_4)_2(THF)_5][Ce(BH_4)_4(THF)_2][J]. Journal of Rare Earths 2012(08)
- [23].Segregation behavior and embrittling effect of lanthanide La, Ce, Pr,and Nd at Σ3(111) tilt symmetric grain boundary in α-Fe[J]. Chinese Physics B 2019(12)
- [24].Photophysical Performance and Energy Transfer Mechanism of a 1-D Chain-like Complex[J]. Chinese Journal of Structural Chemistry 2020(04)
- [25].Synthesis, structure, and magnetic properties of two novel lanthanide-organic frameworks[J]. Science in China(Series B:Chemistry) 2009(09)
- [26].Prediction of thermodynamic properties of actinide and lanthanide compounds[J]. Nuclear Science and Techniques 2008(03)
- [27].Tunable white-light emission of lanthanide(Ⅲ) hybrid material based on hectorite[J]. Chinese Chemical Letters 2018(02)
- [28].Synthetic rubbers prepared by lanthanide coordination catalysts[J]. Science in China(Series B:Chemistry) 2009(10)
- [29].Polymerization of acrylonitrile catalyzed by lanthanide-sodium alkoxide clusters Ln_2(OCH_2CH_2NMe_2)_(12)(OH)_2Na_8 [Ln=Yb (1),Nd (2) and Sm (3)][J]. Chinese Science Bulletin 2011(26)
- [30].Thermal and radiative characteristics of oxyfluoride glass singly doped with lanthanide ions[J]. Journal of Rare Earths 2010(06)