论文摘要
Regiodivergent 1,2-hydroboration of 1,3-dienes with pinacolborane has been accomplished by well-defined cobalt complexes of different bidentate ligands. The iminopyridine-cobalt system is selective for Markovnikov 1,2-hydroboration to form allylboronates, while the FOXAP-cobalt（FOXAP=（S）-1-（diphenylphosphino）-2-[（S）-4-isopropyloxazolin-2-yl]ferrocene） catalyst effects the complementary anti-Markonikv 1,2-hydroboration to afford homoallyboronates with high regioselectivity.
论文目录
文章来源
类型: 期刊论文
作者: Sihan Peng,Ji Yang,Guixia Liu,Zheng Huang
来源: Science China(Chemistry) 2019年03期
年度: 2019
分类: 工程科技Ⅰ辑
专业: 化学
单位: State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry,School of Physical Science and Technology, Shanghai Tech University
基金: supported by the National Key R&D Program of China (2016YFA0202900,2015CB856600),the National Natural Science Foundation of China (21825109,21432011,21572255,21732006),Chinese Academy of Sciences (XDB20000000,QYZDB-SSWSLH016),Science and Technology Commission Shanghai Municipality (17JC1401200)
分类号: O621.251
页码: 336-340
总页数: 5
文件大小: 840K
下载量: 10
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